Publications

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1688 Publications visible to you, out of a total of 1688

Abstract

Not specified

Authors: O. Vaduvescu, A. Aznar Macias, T. G. Wilson, T. Zegmott, F. M. Pérez Toledo, M. Predatu, R. Gherase, V. Pinter, F. Pozo Nunez, K. Ulaczyk, I. Soszyński, P. Mróz, M. Wrona, P. Iwanek, M. Szymanski, A. Udalski, F. Char, H. Salas Olave, G. Aravena-Rojas, A. C. Vergara, C. Saez, E. Unda-Sanzana, B. Alcalde, A. de Burgos, D. Nespral, R. Galera-Rosillo, N. J. Amos, J. Hibbert, A. López-Comazzi, J. Oey, M. Serra-Ricart, J. Licandro, M. Popescu

Date Published: 1st Oct 2022

Publication Type: Journal

Abstract

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Authors: Sonja Schanzer, Martin Koch, Andreas Kiefer, Thalia Jentke, Michael Veith, Franz Bracher, Johannes Bracher, Christoph Müller

Date Published: 1st Oct 2022

Publication Type: Journal

Abstract (Expand)

erroptosis is a type of cell death caused by radical-driven lipid peroxidation, leading to membrane damage and rupture. Here we show that enzymatically produced sulfane sulfur (S0) species, specifically hydropersulfides, scavenge endogenously generated free radicals and, thereby, suppress lipid peroxidation and ferroptosis. By providing sulfur for S0 biosynthesis, cysteine can support ferroptosis resistance independently of the canonical GPX4 pathway. Our results further suggest that hydropersulfides terminate radical chain reactions through the formation and self-recombination of perthiyl radicals. The autocatalytic regeneration of hydropersulfides may explain why low micromolar concentrations of persulfides suffice to produce potent cytoprotective effects on a background of millimolar concentrations of glutathione. We propose that increased S0 biosynthesis is an adaptive cellular response to radical-driven lipid peroxidation, potentially representing a primordial radical protection system.

Authors: Uladzimir Barayeu, Danny Schilling, Mohammad Eid, Thamara Nishida Xavier da Silva, Lisa Schlicker, Nikolina Mitreska, Christopher Zapp, Frauke Gräter, Aubry K. Miller, Reinhard Kappl, Almut Schulze, José Pedro Friedmann Angeli, Tobias P. Dick

Date Published: 15th Sep 2022

Publication Type: Journal

Abstract (Expand)

CO oxidation on Ru(0001) is a long-standing example of a reaction that, being thermally forbidden in ultrahigh vacuum, can be activated by femtosecond laser pulses. In spite of its relevance, the precise dynamics of the photoinduced oxidation process as well as the reasons behind the dominant role of the competing CO photodesorption remain unclear. Here we use ab initio molecular dynamics with electronic friction that account for the highly excited and nonequilibrated system created by the laser to investigate both reactions. Our simulations successfully reproduce the main experimental findings: the existence of photoinduced oxidation and desorption, the large desorption to oxidation branching ratio, and the changes in the O K-edge X-ray absorption spectra attributed to the initial stage of the oxidation process. Now, we are able to monitor in detail the ultrafast CO desorption and CO oxidation occurring in the highly excited system and to disentangle what causes the unexpected inertness to the otherwise energetically favored oxidation.

Authors: Auguste Tetenoire, Christopher Ehlert, J. I. Juaristi, Peter Saalfrank, M. Alducin

Date Published: 15th Sep 2022

Publication Type: Journal

Abstract

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Authors: Joanna Panecka-Hofman, Ina Poehner, Rebecca C. Wade

Date Published: 2nd Sep 2022

Publication Type: Journal

Abstract

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Authors: T. Shenar, H. Sana, L. Mahy, J. Maı́z Apellániz, Paul A. Crowther, M. Gromadzki, A. Herrero, N. Langer, P. Marchant, F. R. N. Schneider, K. Sen, I. Soszyński, S. Toonen

Date Published: 1st Sep 2022

Publication Type: Journal

Abstract

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Authors: Tomer Shenar, Hugues Sana, Laurent Mahy, Kareem El-Badry, Pablo Marchant, Norbert Langer, Calum Hawcroft, Matthias Fabry, Koushik Sen, Leonardo A. Almeida, Michael Abdul-Masih, Julia Bodensteiner, Paul A. Crowther, Mark Gieles, Mariusz Gromadzki, Vincent Hénault-Brunet, Artemio Herrero, Alex de Koter, Patryk Iwanek, Szymon Kozłowski, Daniel J. Lennon, Jesús Maı́z Apellániz, Przemysław Mróz, Anthony F. J. Moffat, Annachiara Picco, Paweł Pietrukowicz, Radosław Poleski, Krzysztof Rybicki, Fabian R. N. Schneider, Dorota M. Skowron, Jan Skowron, Igor Soszyński, Michał K. Szymański, Silvia Toonen, Andrzej Udalski, Krzysztof Ulaczyk, Jorick S. Vink, Marcin Wrona

Date Published: 1st Sep 2022

Publication Type: Journal

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