Fine-Tuned Organic Photoredox Catalysts for Fragmentation-Alkynylation Cascades of Cyclic Oxime Ethers

Abstract:

Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers. The redox properties of the dyes were determined by both cyclic voltammetry and computation and covered an existing gap in the oxidation potential of photoredox organocatalysts.

SEEK ID: https://publications.h-its.org/publications/496

DOI: 10.1039/C8SC01818A

Research Groups: Computational Carbon Chemistry

Publication type: Journal

Journal: Chemical Science

Citation: Chem. Sci. 9(27):5883-5889

Date Published: 2018

Registered Mode: by DOI

Authors: Franck Le Vaillant, Marion Garreau, Stefano Nicolai, Ganna Gryn'ova, Clemence Corminboeuf, Jerome Waser

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Citation
Le Vaillant, F., Garreau, M., Nicolai, S., Gryn'ova, G., Corminboeuf, C., & Waser, J. (2018). Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers. In Chemical Science (Vol. 9, Issue 27, pp. 5883–5889). Royal Society of Chemistry (RSC). https://doi.org/10.1039/c8sc01818a
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Created: 5th Nov 2019 at 13:39

Last updated: 5th Mar 2024 at 21:23

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