Publications

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1579 Publications visible to you, out of a total of 1579

Abstract

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Authors: Andreas Bauswein, Nikolaos Stergioulas, Hans-Thomas Janka

Date Published: 1st Mar 2016

Publication Type: Journal

Abstract

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Authors: Babette Regierer, Susanne Hollmann, Martin Golebiewski

Date Published: 9th Feb 2016

Publication Type: Journal

Abstract

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Authors: Khalid Mohammed Khan, Mohammad A. Mesaik, Omer M. Abdalla, Fazal Rahim, Samreen Soomro, Sobia A. Halim, Ghulam Mustafa, Nida Ambreen, Ahmad Shukralla Khalid, Muhammad Taha, Shahnaz Perveen, Muhammad Tanveer Alam, Abdul Hameed, Zaheer Ul-Haq, Hayat Ullah, Zia Ur Rehman, Rafat Ali Siddiqui, Wolfgang Voelter

Date Published: 1st Feb 2016

Publication Type: Journal

Abstract (Expand)

We show that, all other conditions being equal, bond cleavage in the middle of molecules is entropically much more favored than bond cleavage at the end. Multiple experimental and theoretical approaches have been used to study the selectivity for bond cleavage or dissociation in the middle versus the end of both covalent and supramolecular adducts and the extensive implications for other fields of chemistry including, e.g., chain transfer, polymer degradation, and control agent addition are discussed. The observed effects, which are a consequence of the underlying entropic factors, were predicted on the basis of simple theoretical models and demonstrated via high‐temperature (HT) NMR spectroscopy of self‐assembled supramolecular diblock systems as well as temperature‐dependent size‐exclusion chromatography (TD SEC) of covalently bonded Diels–Alder step‐growth polymers.

Authors: Kai Pahnke, Josef Brandt, Ganna Gryn'ova, Ching Y. Lin, Ozcan Altintas, Friedrich G. Schmidt, Albena Lederer, Michelle L. Coote, Christopher Barner-Kowollik

Date Published: 22nd Jan 2016

Publication Type: Journal

Abstract

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Authors: Rafiullah Rafiullah, Muhammad Aslamkhan, Nagarajan Paramasivam, Christian Thiel, Ghulam Mustafa, Stefan Wiemann, Matthias Schlesner, Rebecca C Wade, Gudrun A Rappold, Simone Berkel

Date Published: 21st Jan 2016

Publication Type: Journal

Abstract

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Authors: O. Just, M. Obergaulinger, H.-T. Janka, A. Bauswein, N. Schwarz

Date Published: 10th Jan 2016

Publication Type: Journal

Abstract

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Authors: S Goriely, A Bauswein, H-T Janka, S Panebianco, J-L Sida, J-F Lemaître, S Hilaire, N Dubray

Date Published: 5th Jan 2016

Publication Type: Journal

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