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The Interaction Properties of the Human Rab GTPase Family – A Comparative Analysis Reveals Determinants of Molecular Binding Selectivity

Abstract

Not specified

Authors: Matthias Stein, Manohar Pilli, Sabine Bernauer, Bianca H. Habermann, Marino Zerial, Rebecca C. Wade

Date Published: 16th Apr 2012

Publication Type: Journal

Reversible Addition–Fragmentation Chain Transfer Polymerization of Vinyl Chloride

Abstract (Expand)

Controlled/“living” radical polymerization (CLRP) of vinyl chloride (VC) via the reversible addition–fragmentation chain transfer (RAFT) process is reported for the first time. The cyanomethyl … methyl(phenyl)carbamodithioate (CMPCD) was found to be an efficient RAFT agent enabling the CLRP polymerization of VC monomer under certain experimental conditions. Two different radical initiators, having very distinct half-life times at room temperature, were employed in this study. The kinetic studies of RAFT polymerization of VC show a linear increase of the molecular weight with the monomer conversion and the lowest polydispersity (PDI) ever reported for poly(vinyl chloride) (PVC) synthesized with CLRP method (PDI ∼ 1.4). The resulting PVC was fully characterized using the matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS), 1H nuclear magnetic resonance spectroscopy (1H NMR), and gel permeation chromatography (GPC) techniques. The 1H NMR and MALDI-TOF-MS analysis of PVC prepared via RAFT polymerization method have shown the absence of structural defects and the presence of chain-end functional groups. The “livingness” of the PVC was also confirmed by a successful reinitiation experiment. The suitability of the RAFT agent was also confirmed via high-level ab initio molecular orbital calculations.

Authors: Carlos M. R. Abreu, Patrícia V. Mendonça, Arménio C. Serra, Jorge F. J. Coelho, Anatoliy V. Popov, Ganna Gryn’ova, Michelle L. Coote, Tamaz Guliashvili

Date Published: 27th Feb 2012

Publication Type: Journal

Atomic Detail Brownian Dynamics Simulations of Concentrated Protein Solutions with a Mean Field Treatment of Hydrodynamic Interactions

Abstract

Not specified

Authors: Paolo Mereghetti, Rebecca C. Wade

Date Published: 8th Feb 2012

Publication Type: Journal

Allosterically Gated Enzyme Dynamics in the Cysteine Synthase Complex Regulate Cysteine Biosynthesis in Arabidopsis thaliana

Abstract

Not specified

Authors: Anna Feldman-Salit, Markus Wirtz, Esther D. Lenherr, Christian Throm, Michael Hothorn, Klaus Scheffzek, Rüdiger Hell, Rebecca C. Wade

Date Published: 1st Feb 2012

Publication Type: Journal

Multiple, Ligand-dependent Routes from the Active Site of Cytochrome P450 2C9

Abstract

Not specified

Authors: Vlad Cojocaru, Peter J. Winn, Rebecca C. Wade

Date Published: 1st Feb 2012

Publication Type: Journal

Dynamische hybride Cloud für wissenschaftliche Anwendungen

Abstract

Not specified

Author: Thomas Monninger

Date Published: 2012

Publication Type: Master's Thesis

Black Hole Mass Estimates Based on C IV are Consistent with Those Based on the Balmer Lines

Abstract

Not specified

Authors: R. J. Assef, K. D. Denney, C. S. Kochanek, B. M. Peterson, S. Kozłowski, N. Ageorges, R. S. Barrows, P. Buschkamp, M. Dietrich, E. Falco, C. Feiz, H. Gemperlein, A. Germeroth, C. J. Grier, R. Hofmann, M. Juette, R. Khan, M. Kilic, V. Knierim, W. Laun, R. Lederer, M. Lehmitz, R. Lenzen, U. Mall, K. K. Madsen, H. Mandel, P. Martini, S. Mathur, K. Mogren, P. Mueller, V. Naranjo, A. Pasquali, K. Polsterer, R. W. Pogge, A. Quirrenbach, W. Seifert, D. Stern, B. Shappee, C. Storz, J. Van Saders, P. Weiser, D. Zhang

Date Published: 1st Dec 2011

Publication Type: Journal

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